Publicações recentes

 

 

Homo- and Heteronuclear Compounds with a Symmetrical Bis-Hydrazone Ligand: Synthesis, Structural Studies and Luminiscence Properties, S. Rodríguez-Hermida, A.B. Lago, R. Carballo, O. Fabelo, E.M. Vázquez-López, Chem.-Eur. J., 21, 6605-6616 (2015).

 

 

Alkali-Metal-Ion-Directed Self-Assembly of Redox-Active Manganese(III) Supramolecular Boxes, G. González-Riopedre, M. R. Bermejo, M. I. Fernández-García, A. M. González-Noya, R. Pedrido, M. J. Rodríguez-Doutón, M. Maneiro, Inorg. Chem., 54, 2512-2521 (2015).

 

 

Lights and shadows in the challenge of binding acyclovir, a synthetic purine-like nucleoside with antiviral activity, at an apical–distal coordination site in copper(II)-polyamine chelates, I. Pérez-Toro, A. Domínguez-Martín, D. Choquesillo-Lazarte, E. Vílchez-Rodríguez, J. M. González-Pérez, A. Castiñeiras, J. Niclós-Gutiérrez, J. Inorg. Biochem., 148, 84-92 (2015).

 

Tin Oxometallates from the Hydrolysis of SnMe22+ in the Presence of 2,6-Lutidine-α2,3-diol and Different Anions, J. S. Casas, A. Castiñeiras,  F. Condori, M. D. Couce,  A. Sánchez,  J. Sordo,  E. M. Vázquez-López, Eur. J. Inorg. Chem., 2387-2401 (2015).

 


Structural studies and bioactivity of diorganotin(IV) complexes of pyridin-2-thionato derivatives, S. Barreiro, M. L. Durán-Carril, J. Viqueira, A. Sousa-Pedrares, J. A. García-Vázquez, J. Romero, J. Organomet. Chem., 791, 155-162 (2015).

 

 

 

Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties, F. Ragon, B.C. Campo, Q. Yang, Ch. Martineau, A. Wiersum, A.B. Lago, V. Guillerm, C. Hemsley, J.F. Eubank, M. Vishnuvarthan, F. Taulelle, P. Horcajada, A. Vimont, P. Llewellyn, M. Daturi, S. Devautour-Vinot, G. Maurin, Ch. Serre, T. Devic, G. Clet, J. Mat. Chem. A, 3, 3294-3309 (2015).

 

 


New diorganolead(IV) sulfanylpropenoates: Synthesis, characterization and analysis of their evolution in DMSO solution, J.S. Casas, M.V. Castaño, M.D. Couce, A. Sánchez, J. Sordo, M.D. Torres, E.M. Vázquez-López, J. Organomet. Chem., 789-790, 29-39 (2015).

 

 

 

External anion effect on the synthesis of new MOFs based on formate and a twisted divergent ligands, A.B. Lago, R. Carballo, L. Lezama, E.M. Vázquez-López, J. Sol. State Chem., 231, 145-151 (2015).

 

 

 

Two Novel Unsymmetrical Ferrocene Based Azines and Their Complexing Abilities Towards Cu(II): Spectroscopy, Crystal Structure, Electrochemistry and DFT Calculations M. Emirika, K. Karaoglua, K. Serbesta, U. Coruh, E.M. Vázquez-López, Polyhedron, 88, 182-189 (2015)

 

 

Metal complexes with N-(trifluoromethylbenzyl)iminodiacetate chelators (x-3F ligands). Part I. Copper(II) chelates of p-3F, m-3F, and o-3F with or without imidazole-like ligandsM. Serrano-Braceras, D. Choquesillo-Lazarte, A. Domínguez-Martín, E. Vílchez-Rodríguez, M. E. García-Rubiño, J. M. González-Pérez, A. Castiñeiras, J. Niclós-Gutiérrez, J. Coord. Chem., 68, 2739-2759 (2015).

 

Exploration of the solid state metallosupramolecular chemistry of mononuclear nickel(II) complexes with α-hydroxycarboxylates and 2,2′-dipyridylamine, R. Carballo, B. Covelo, A. B. Lago, A. Pino-Cuevas, E. M. Vázquez-López, Polyhedron, 85, 124-130 (2015).

 

 

Rhenium Complexes of LIgands Based on Stilbene - Synthesys, Characterization, Reactivity, and Conformational AnalysisHomo- and Heteronuclear Compounds with a Symmetrical Bis-Hydrazone Ligand: Synthesis, Structural Studies and Luminiscence Properties, A. Pino-Cuevas, R. Carballo, L. Muñoz, E.M. Vázquez-López, Eur. J. Inorg. Chem., 4402-4411 (2015).

 

Mono and dinuclear phosphinegold(I) sulfanylcarboxylates: The effect of substituing PPh3 for PEt3 on cytotoxicity, E. Barreiro, J.S. Casas, M.D. Couce, A. Sánchez, A. Sánchez-González, J. Sordo, E.M. Vázquez-López, J. Inorg. Biochem., 138, 89-98 (2014).

 

The regulation of the oxidative phase of the pentose phosphate pathway: New asnwers to old problems, R. Barcia, J. I. Ramos-Martínez, IUBMB Life, 66, 775-779 (2014).

 

Heteronuclear gold(I)-silver(I) sulfanylcarboxilates: Synthesis, structure and cytotoxic activity against cancer cell lines, E. Barreiro, J. S. Casas, M. D. Couce, A. Sánchez, J. Sordo, E. M. Vázquez-López, J. Inorg. Biochem., 131, 68-75 (2014).

 

Two Novel Ternary Dicopper(II) μ-Guanazole Complexes with Aromatic Amines Strongly Activated by Quantum Dots for DNA Cleavage, J. Hernández-Gil, S. Ferrer, A. Castiñeiras, M. Liu-González, F. Lloret, A. Ribes, L. Coga, A. Bernecker, J. C. Mareque-Rivas, Inorg. Chem., 53, 578-593 (2014).

Synthesis, thermogravimetric study and crystal structure of an N-rich copper(II) compound with tren ligands and nitrate counter-anions, I. Pérez-Toro, A. Domínguez-Martín, D. Choquesillo-Lazarte, E.  Vílchez-Rodriguez, A. Castiñeiras, J. Niclós-Gutiérrez, Thermochimica Acta, 593, 7-11 (2014).

 

 

 

Coordination variability of CuI in multidonor heterocyclic thioamides: synthesis, crystal structures, luminescent properties and ESI-mass studies of complexes, T. S. Lobana, A. K. Sandhu, R. Sultana, A. Castiñeiras, R. J. Butcher, J. P. Jasinski, RSC Advances, 4, 30511-30522 (2014).

 

Metallo-Supramolecular Structures by Self-Assembly through Weak Interactions in Mixed Ligand Metal Complexes of Adenine and Malonate, H. El Bakkali, A. Castiñeiras, I. García-Santos, J. M. González-Pérez, J. Niclós-Gutiérrez, Cryst. Growth Des., 14, 249-260 (2014).

 

Cocrystallization of Mononuclear and Trinuclear Metallacycle Molecules from an Aqueous Mixed-Ligand Copper(II) Solution, H. El Bakkali, D. Choquesillo-Lazarte, A. Domínguez-Martín, M. I. Pérez-Toro, L. Lezama, J. M. González-Pérez, A. Castiñeiras, J. Niclós-Gutiérrez, Cryst. Growth Des., 14, 889-892 (2014).

 

 

Unprecedented 4/5-methylimidazole linkage isomerism within a binuclear copper(II) complex molecule, H. El Bakkali, A. Dominguez-Martín, D. Choquesillo-Lazarte, E. Vílchez-Rodríguez, J. M. González-Pérez, A. Castiñeiras, J. Niclós-Gutiérrez, Inorg. Chem. Commun., 42, 20-22 (2014).

 

Synthesis, structure and spectroscopy of mono- and di-nuclear copper(I) complexes incorporating anionic thiophene based thiosemicarbazones-first examples, T. S. Lobana, S. Indoria, M. Sharma, J. Nandi, A. K. Jassal, M. S. Hundal, A. Castiñeiras, Polyhedron, 80, 34-40 (2014).

 

Supramolecular interactions in biologically relevant compounds. 2-Pyrazineformamide thiosemicarbazones and some products of their cyclization, A. Castiñeiras, I. García-Santos, S. Nogueiras, I. Rodríguez-González, R. Rodríguez-Riobó, J. Mol. Struct., 1074, 1-18 (2014).

 

Copper(II) Acetate/Bis(4-pyridylthio)methane System: Synthesis, Structural Diversity, and Single-Crystal to Single-Crystal Transformation, A. B. Lago, R. Carballo, S. Rodríguez-Hermida, E. M. Vázquez-López, Cryst. Growth Des., 14, 3096-3109 (2014).

 

Synthesis, characterization and binding affinities of rhenium(I) thiosemicarbazone complexes for the estrogen receptor (α/β), A. Núñez-Montenegro, R. Carballo, E. M. Vázquez-López, J. Inorg. Biochem., 140, 53-63 (2014).

 

Crystal structure of 1-(4-formylbenzylidene)-4-methylthiosemicarbazone, A. Pino-Cuevas, R. Carballo, E. M. Vázquez-López, Acta. Cryst., E70, o926 (2014).

 

 

Crystal structure of 1-(4-formylbenzylidene)thiosemicarbazone, R. Carballo, A. Pino-Cuevas, E. M. Vázquez-López, Acta. Cryst., E70, 0970 (2014).

Structural evidence of an intramolecular proton transfer leading to keto-amine tautomer in the crystals of Schiff bases derived from tyrosine and histidine esters, A Núñez-Montenegro, A. Pino-Cuevas, R. Carballo, E. M. Vázquez-López, J. Mol. Struct., 1062, 110-115 (2014).

 

 

 

Synthesis, characterization and in vitro toxicity assessment of DMPS-capped CdTe quantum dots, J. S. Casas, M. S. García-Tasende, A. Sánchez, A. Sánchez, J. Sordo, A. Touceda, M. Vázquez-González, Polyhedron, 70, 77-84 (2014).

 

Fluorescence of New o-Carborane Compounds with Different Fluorophores: Can it be Tuned?, A. Ferrer-Ugalde, A. González-Campo, C. Viñas, J. Rodríguez-Romero, R. Santillan, N. Farfán, R. Sillanpää, A. Sousa-Pedrares, R. Núñez, F. Teixidor, Chem. Eur. J. , 20, 9940-9951 (2014).

 

 

Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph3Sn{Ph2PC6H4S-2}], [Sn{PhP(C6H4S-2)2}2] and [Pb{Ph2P(O)C6H4S-2}2]·1/2CH3OH·2H2O complexes, P. Fernández, J. Romero, J. A. García-Vázquez, A. Sousa-Pedrares, L. Valencia, J. Zubieta, P. Pérez-Lourido, J. Organomet. Chem., 750, 1-6 (2014).

 

 

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Coordination of α-hydroxycarboxylic acids with first-row transition ions, E. Bermejo, R. Carballo, A. Castiñeiras, A. B. Lago, Coord. Chem. Rev., 257, 2639-2651 (2013).

 

Aurophilicity in gold(I) thiosemicarbazone clusters, A. Castiñeiras, R. Pedrido, Dalton Trans., 41, 1363-1372 (2012).

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Coordination Chemistry of Vitamin B6 and Derivatives: A Structural Overview, José S. Casas, Mª. Delfina Couce, José Sordo, Coord. Chem. Rev. 256, 3036-3062 (2012).

 

Sensitivity of the kinase activity of human vaccinia-related kinase proteins to toxic metals, I. Barcia-Sanjurjo, M. Vázquez-Cedeira,  R. Barcia, P. A. Lazo, JBIC Journal of Biological Inorganic Chemistry, 18, 473-482 (2013).

Electrochemical synthesis and structural characterization of  homoleptic and  heteroleptic cobalt, nickel, copper, zinc and cadmium compounds with the 2-hydroxy-1,4-naphtquinona, I. Casanova, A. Sousa-Pedrares, J. Viqueira, M. L. Durán, J. Romero, A. Sousa, J. A. García-Vázquez, New J. Chem, 37, 2303-2316 (2013).

 

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Unravelling the versatile metal binding modes of adenine: Looking at the molecular recognition patterns of deaza- and aza-adenines in mixed ligand metal complexes, A. Domínguez-Martín, M. P. Brandi-Blanco, A. Matilla-Hernandez, H. El Bakkali, V. M. Nurchi,  J. Gonzalez-Perez, A. Castiñeiras, J. Niclós-Gutiérrez, Coord. Chem. Rev., 257, 2814-2838 (2013).

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A Unique Discrete Tetranuclear Cu'-Cu(N-N)2Cu-Cu' Copper(II) Complex, Built from a μ3-1,2,4-Triazolato-μ-carboxylato Ligand, as an Effective DNA Cleavage Agent, J. Hernández-Gil, S. Ferrer, A. Castiñeiras, F. Lloret, Inorg. Chem., 51, 9809-9819 (2012).

 

Graphical abstract: A sequentially assembled grid composed of supramolecular meso-helical nodes

A sequentially assembled grid composed of supramolecular meso-helical nodes, M. Martínez-Calvo, R. Pedrido, A. M. González-Noya, M. J. Romero, M. Cwiklinska, G. Zaragoza, M. R. Bermejo, Chem. Commun., 47, 9633-9635 (2011).

 

Graphical abstract: Manganese-Schiff base complexes as catalysts for water photolysis

Manganese-Schiff base complexes as catalysts for water photolysis, G. González-Riopedre, M. I. Fernández-García, A. M. González-Noya, M. A. Vázquez-Fernández, M. R. Bermejo, M. Maneiro, Phys. Chem. Chem. Phys., 13, 18069-18077 (2011).

 

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Influence of the geometry around de manganese ions on the peroxidase and the catalase activities of Mn(III)-Schiff base complexes, M. A. Vázquez-Fernández, M. R. Bermejo, M. I. Fernández-García, G. González-Riopedre, M. J. Rodríguez-Doutón, M. Maneiro, J. Inorg. Biochem., 105, 1538-1547 (2011).


 

Differential inhibitor sensitivity between human kinases VRK1 and VRK2, M. Vázquez-Cedeira, I. Barcia-Sanjurjo, M. Sanz-García, R. Barcia, P. A. Lazo, PloS ONE, 6, e23235 (2011).

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Synthesis, crystal structures and spectroscopy of meclofenamic acid and its metal complexes with manganese(II), copper(II), zinc(II) and cadmium(II). Antiproliferative and superoxide dismutase activity, D. Kovala-Demertzi, M. Staninska, I. García-Santos, A. Castiñeiras, M. A. Demertzis, J. Inorg. Biochem., 105, 1187-1195 (2011).

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Molecular recognition patterns of 2-aminopurine versus adenine: A view through ternary copper(II) complexes, A. Domínguez-Martín, D. Choquesillo-Lazarte, J. M. González-Pérez, J. M. Castiñeiras, J. Niclós-Gutiérrez, J. Inorg. Biochem., 105, 1073-1080 (2011).

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Chelating ligand conformation driving the hypoxanthine metal binding patterns, D. K. Patel, D. Choquesillo-Lazarte, A. Dominguez-Martin, M. P. Brandi-Blanco, J. M. González-Perez, A. Castiñeiras, J. Niclós-Gutiérrez, Inorg. Chem., 50, 10549-10551 (2011).